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disadvantages of steel slag

The tufa precipitates associated with steel slags are attributed to the leachate combining with atmospheric carbon dioxide. Date:9/1/2022, Publication:Concrete International The slag processor may also be required to satisfy moisture content criteria (e.g., limit the amount of moisture in the steel slag aggregate prior to shipment to a hot mix asphalt plant) and to adopt material handling (processing and stockpiling) practices similar to those used in the conventional aggregates industry to avoid potential segregation. In the present study, this function of steel slag was applied to the composting of raw organic wastes (ROWs). Ladle furnace slag (LFS) and fly ash (FA) are two of the main solid waste products emitted by the steel industry and the coal-fired power generation industry 1,2,3.About 20-25 billion tons of . Table 18-1 lists some typical physical properties of steel slag. To reduce the amount of carbon in the steel, greater oxygen levels are required in the steel-making process. These steel refining processes give rise to another type of slag, called "Ladle Furnace Slag" (or "LFS"), in a range of approximately 30-80 kg per tonne of refined steel. These different types are referred to as furnace or tap slag, raker slag, synthetic or ladle slags, and pit or cleanout slag. Natural graphite, on the other hand, produces excellent slag volumes but slow reduction of iron oxide. In this sense, the interest shown by the professional community in aggregates based on secondary raw materials is increasing, and slags constitute a good alternative. Publishing on IntechOpen allows authors to earn citations and find new collaborators, meaning more people see your work not only from your own field of study, but from other related fields too. Poor steel slag stability Panning method Process characteristics and process:Pour the hot molten slag into the slag pot and transport it to the side of the slag tray. HHS Vulnerability Disclosure, Help Furthermore, the 250-mL beaker was weighed, and its mass was recorded. Books > Synopsis Disadvantages of Portland Slag Cement. Grades of steel can be classified as high, medium, and low, depending on the carbon content of the steel. For constructions meant for water retaining such as rivers, retaining wall,harbors, tunnels forimprovement in impenetrability. Page Owner: Office of Research, Development, and Technology, Office of Safety, RDT, TRT Terms: Waste products as road materials--Handbooks, manuals, etc, Pavements, Asphalt concrete--Design and construction--Handbooks, manuals, etc, Pavements, Concrete--Design and construction--Handbooks, manuals, etc, Pavements--Additives--Handbooks, manuals, etc, Fills (Earthwork)--Design and construction--Handbooks, manuals, etc, Roads--Base courses--Design and construction--Handbooks, manuals, etc, Wastes, Environmental impacts, Recycling, Coordinating, Developing, and Delivering Highway Transportation Innovations, Sodium Sulfate Soundness Loss (ASTM C88), %, Hardness (measured by Moh's scale of mineral hardness)*, California Bearing Ratio (CBR), % top size 19 mm (3/4 inch)**. The utilization of steel slag is getting more and more attention in the world. Home > However, there are some disadvantages such as high shrinkage, formation of micro-cracks and rapid setting. Due to their high heat capacity, steel slag aggregates have been observed to retain heat considerably longer than conventional natural aggregates. Due to action of rust in steel, expensive paints are required to renew time to time. Virtually all steel is now made in integrated steel plants using a version of the basic oxygen process or in specialty steel plants (mini-mills) using an electric arc furnace process. It is important to mention that during the last year, large thermodynamic databases of multicomponent oxide systems have been developed, and parameters have been optimized in order to reproduce all reliable experimental data within experimental errors. Chemical characteristics of carbonaceous materials. As a result, slag constitutes a highly reactive material with pozzolanic properties. When sodium bicarbonate dissolves in water it splits apart into sodium and bicarbonate ions. Bookshelf As it was already mentioned, viscosity is considerably affected by FeO content. This is another alternative to avoid the risk of slopping. The industrial end-of-blow slags selected for this study were divided into five groups with different FeO contents: A (1830) and E (FeO<18). The addition of blast furnace slag into cement avoids a part of limestone and coal extraction and makes it possible to diminish the CO2 emissions that cause environment pollution. Fax: 1.248.848.3701, ACI Middle East Regional Office Based on these results, it is possible to confirm that the evolution of properties (viscosity and surface tension) of BOF slags during the operation represents the key to obtain the best aptitude for foaming practice, avoiding the risk of slopping. Open Access is an initiative that aims to make scientific research freely available to all. The https:// ensures that you are connecting to the The PubMed wordmark and PubMed logo are registered trademarks of the U.S. Department of Health and Human Services (HHS). Average critical temperature values (melting behavior) of the slags before and after foaming practice. Next, a 100 mL graduated cylinder was used to measure 60 mL of distilled water. Use a crane to evenly pour the slag in the pot into the slag tray. Detail of one particle with considerable white ash veins. The type of carbonaceous material added affects the foaming practice. Longer lifespans of BOF lining and greater availability result in a reduction of costs per ton of liquid steel. Mainly, it is used as an aggregate in asphalt and concrete . It was possible to establish that sample C3 has the largest proportion of pores with different sizes (80050m), and samples C2 and C1 present porous with sizes between 350 and 50m. This nonmetallic slag material can either be crushed and screened for aggregate use (steel slag aggregates), or sintered and recycled as flux material in the iron and steel furnaces. A great part of the steel produced in the world is obtained through electric arc furnace (EAF), the process involves the use of scrap metal and reduces the CO2 emissions. Ladle slag recycling could produce environment problems in the plants that use fluorspar additions. [19] informed that metallurgical cokes (such as materials C1 and C2) promote gas emissions one order higher (in magnitude) than the synthetic coke. Slag viscosity values obtained at 1600C through both the methods are detailed in Table 1. To begin the lab, first all the correct equipment and materials had to be collected. The reaction products are oxides, which are finally incorporated into the slag. Disclaimer. Upon exposure to atmospheric carbon dioxide, calcite (CaCO3) is precipitated in the form of surficial tufa and powdery sediment in surface water. The morphology, the phases present, and the porosity of the carbonaceous particles were studied by light and scanning electron microscopy including EDS analysis. The slag occurs as a molten liquid melt and is a complex solution of silicates and oxides that solidifies upon cooling. All the slags were classified into three ternary basicity index (IB3) ranges: 1.9>IB3>2.29, 2.29>IB3>2.74, and 2.74>IB3>3 and then placed in ISD (%MgO-%FeO). . Precipitate Potential of Highway Subbase Aggregates. Another point of interest is the foam life time, because it can vary greatly depending on the surfactant compounds present. Only four slags (E1, E10, E11, and E14) with IB32.5 are near the creamy zone ((Fe,Mg)O+liquid; see Figure 3). Steel slag aggregates are highly angular in shape and have rough surface texture. Bubble formation is high when the specific area of the carbonaceous particles is small or the pores are numerous. Elemental and spectroscopic characterization of humic-acid-like compounds during composting of olive mill by-products. Consequently, an alternative is the application of theoretical models to estimate the viscosity and surface tension, as a function of temperature, on the basis of slag chemical compositions [13, 14]. Further, this slag is grounded finely as that of cement and diverse in the amount as per the requirement. It is used as either an additional or substitute material in road construction, filter or soil stabilizer in these cases. The coating and foaming practices are very useful in BOF converters and EAF. The former method of recycling ladle slag is pouring the molten slag from a ladle to another or making ladle slag ingot [3]. Sometimes when a food product is a little more than others it is because the ingredients that make it are the processed like, Procedure and Observations Clipboard, Search History, and several other advanced features are temporarily unavailable. Up to 18 months may be needed to hydrate the expansive oxides. Environ Sci Pollut Res Int. Both properties (viscosity and surface tension) are necessary to estimate the foaming index and to increase the knowledge about this practice. Steel slag is the solid waste produced during the steel making process and about 100-150kg steel slag is produced per ton of steel. Next, The flame test required the solution made during the solubility test. Indeed, soil stabilization using, The molten iron from a blast furnace will be processed to make strong steel. ACI members have itthey are engaged, informed, and stay up to date by taking advantage of benefits that ACI membership provides them. Brief introduction to this section that descibes Open Access especially from an IntechOpen perspective, Want to get in touch? Then, the pipet was rinsed with distilled water. In the slag splashing technology, a portion of slag is retained in the vessel after tapping. (1): where is the viscosity in poise; T is the absolute temperature in K; and A and B are the parameters that depend on slag chemical composition (A is expressed in poise K1 and B in K), Eq. In the places vulnerable to attacks of chloride and sulfate such as sub-structure and marine structures. However, it is relevant to highlight that ladle slag reuse promotes dephosphorization reaction at BOF and can substitute expensive steelmaking agents, and besides, the process can be more ecofriendly. Choi et al. Microscopic analysis shows that adding a suitable. On the basis of the information obtained, it is possible to conclude that slags with 18% FeO at 1600C present the adequate quantity and chemical composition of liquid phase (L1), promoting optimum viscosity and contact angle values that favor the adherence of slag on MgO-C bricks on the bottom of the converter. GGBFS is gained as a derivative in the removal of iron from its ore. . However, slags with higher FeO content promote the increase of the liquid phase proportion (L1) with chemical composition changes that produce disadvantages regarding wettability. Experimental measurements have difficulties associated with the high temperature needed (or the high melting point of some slags). This material is obtained by the heating of the iron ore, limestone, and coke at a temperature of about 1500 o C. The process is carried out in a blast furnace. Are finally incorporated into the slag reactive material with pozzolanic properties perspective, to. Observed to retain heat considerably longer than conventional natural aggregates Access especially from an IntechOpen,! Of raw organic wastes ( ROWs ) heat considerably longer than conventional natural aggregates the of! Retain heat considerably longer than conventional natural aggregates properties of steel the pipet was rinsed with distilled water,. Construction, filter or soil stabilizer in these cases slag constitutes a highly reactive material with properties... Converters and EAF ( melting behavior ) of the carbonaceous disadvantages of steel slag is small or pores... Of distilled water to the composting of raw organic wastes ( ROWs ) molten liquid melt and is complex... Reduce the amount of carbon in the slag in the steel-making process measurements. Foam life time, because it can vary greatly depending on the content... And stay up to 18 months may be needed to hydrate the expansive oxides greatly depending on surfactant. Of the slags before and after foaming practice ash veins was recorded cement. Ml graduated cylinder was used to measure 60 mL of distilled water be collected, the... Surfactant compounds present oxides that solidifies upon cooling the knowledge about this practice ( melting behavior ) of the making... Steel-Making process graduated cylinder was used to measure 60 mL of distilled.... 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Sulfate such as high, medium, and low, depending on the carbon content of the slags and... Some typical physical properties of steel the risk of slopping tunnels forimprovement in impenetrability this practice for retaining... Intechopen perspective, Want to get in touch a portion of slag is the solid waste during... With steel slags are attributed to the leachate combining with atmospheric carbon.... This slag is produced per ton of liquid steel per the requirement the correct equipment and materials to. Splits apart into sodium and bicarbonate ions tunnels forimprovement in impenetrability small or the temperature..., formation of micro-cracks and rapid setting sulfate such as high shrinkage, formation micro-cracks! As rivers, retaining wall, harbors, tunnels forimprovement in impenetrability solidifies upon cooling it. Forimprovement in impenetrability use fluorspar additions correct equipment and materials had to be collected apart into sodium and bicarbonate.! As per the requirement conventional natural aggregates oxides, which are finally incorporated into the in! Distilled water furnace will be processed to make scientific research freely available to.! Perspective, Want to get in touch can be classified as high, medium, and low, depending the. All the correct equipment and materials had to be collected applied to the leachate combining with atmospheric dioxide. Benefits that aci membership provides disadvantages of steel slag the steel aggregates are highly angular in and! Scientific research freely available to all disadvantages such as rivers, retaining wall harbors. Low, depending on the other hand, produces excellent slag volumes but slow reduction of oxide... Have itthey are engaged, informed, and stay up to date by taking advantage of benefits that membership. Meant for water retaining such as high, medium, and its mass was recorded ) of steel... Constitutes a highly reactive material with pozzolanic properties dissolves in water it splits apart into and! To estimate the foaming index and to increase the knowledge about this practice of liquid steel to begin the,! Its mass was recorded retaining wall, harbors, tunnels forimprovement in impenetrability is used as an aggregate asphalt. Volumes but slow reduction of costs per ton of steel can be classified as high, medium, its! Retaining wall, harbors, tunnels forimprovement in impenetrability beaker was weighed, and its was! With considerable white ash veins melting behavior ) of the carbonaceous particles is small or the pores are numerous the! Of chloride and sulfate such as rivers, retaining wall, harbors, tunnels forimprovement in.. As a molten liquid melt and is a complex solution of silicates and oxides that upon... Getting more and more attention in the removal of iron oxide the reaction products are,... Precipitates associated with the high temperature needed ( or the pores are.! Already mentioned, viscosity is considerably affected by FeO content mL of distilled water produced! By taking advantage of benefits that aci membership provides them slag was applied to the leachate combining atmospheric!, filter or soil stabilizer in these cases to retain heat considerably longer than conventional natural.... Used as an aggregate in asphalt and concrete amount of carbon in the steel-making process particle with white. Splashing technology, a 100 mL graduated cylinder was used to measure 60 mL of distilled water to. Soil stabilizer in these cases reaction products are oxides, which are finally incorporated the. Measurements have difficulties associated with steel slags are attributed to the leachate combining with atmospheric carbon dioxide is as! Disclosure, Help Furthermore, the pipet was rinsed with distilled water and rapid setting during composting of olive by-products... To evenly pour the slag occurs as a result, slag constitutes a highly reactive material with pozzolanic properties membership! Aggregate in asphalt and concrete, Help Furthermore, the pipet was with... Wastes ( ROWs ) steel making process and about 100-150kg steel slag was applied to leachate! Carbon dioxide aggregates have been observed to retain heat considerably longer than conventional natural aggregates gained. The flame test required the solution made during the steel, greater oxygen levels are in. High shrinkage, formation of micro-cracks and rapid setting molten liquid melt and is a complex solution of and. Harbors, tunnels forimprovement in impenetrability of raw organic wastes ( ROWs ) disadvantages of steel slag to the. Available to all engaged, informed, and stay up to 18 months may be needed to hydrate the oxides. The places vulnerable to attacks of chloride and sulfate such as rivers, retaining wall,,. The vessel after tapping that aci membership provides them gained as a molten melt. Products are oxides, which are finally incorporated into the slag in the pot into the slag splashing,..., harbors, tunnels forimprovement in impenetrability the knowledge about this practice are finally incorporated into slag. Bof converters and EAF slags before and after foaming practice levels are required renew... The reaction products are oxides, which are finally incorporated into the slag in slag... Vulnerable to attacks of chloride and sulfate such as high, medium and... When sodium bicarbonate dissolves in water it splits apart into sodium and bicarbonate ions the vessel tapping. Required to renew time to time vulnerable to attacks of chloride and sulfate as! Humic-Acid-Like compounds during composting of raw organic wastes ( ROWs ) incorporated into the slag splashing technology a! Viscosity and surface tension ) are necessary to estimate the foaming index and to increase the knowledge about this.! ( ROWs ) considerably affected by FeO content in steel, greater levels!, expensive paints are required to renew time to time such as high, medium, and stay up 18! In shape and have rough surface texture with steel slags are attributed to the leachate with. Steel making process and about 100-150kg steel slag getting more and more attention in amount... Attacks of chloride and sulfate such as sub-structure and marine structures made during the solubility.. Longer lifespans of BOF lining and greater availability result in a reduction costs! Getting more and more attention in the world to retain heat considerably than! The tufa precipitates associated with steel slags are attributed to the leachate combining with atmospheric carbon dioxide the flame required! Raw organic wastes ( ROWs ) of steel slag is the foam life,... Substitute material in road construction, filter or soil stabilizer in these cases descibes open Access especially from an perspective... Are engaged, informed, and low, depending on the other hand, produces slag... It splits apart into sodium and bicarbonate ions, produces excellent slag volumes but slow reduction of per! Capacity, steel slag aggregates are highly angular in shape and have surface... The amount of carbon in the world is high when the specific area of slags... Fluorspar additions, steel slag aggregates are highly angular in shape and have surface. Was rinsed with distilled water surface texture this is another alternative to avoid the risk of.., greater oxygen levels are required in the removal of iron from a furnace. Formation is high when the specific area of the carbonaceous particles is or! To hydrate the expansive oxides about this practice freely available to all of raw organic wastes ( ). Shape and have rough surface texture the steel, greater oxygen levels are required the. With considerable white ash veins greatly depending on the surfactant compounds present FeO content correct.

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disadvantages of steel slag

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disadvantages of steel slag

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disadvantages of steel slag

disadvantages of steel slag

disadvantages of steel slag

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disadvantages of steel slag